Crystal system

Crystals can be classified in three ways: lattice systems, crystal systems and crystal families. The various classifications are often confused: in particular the trigonal crystal system is often confused with the rhombohedral lattice system, and the term "crystal system" is sometimes used to mean "lattice system" or "crystal family".

A lattice system is a group of lattices with the same set of lattice point groups. The 14 Bravais lattices are grouped into seven lattice systems: triclinic, monoclinic, orthorhombic, tetragonal, rhombohedral, hexagonal, and cubic.

A crystal system is a set of point groups in which the point groups themselves and their corresponding space groups are assigned to a lattice system. Of the 32 crystallographic point groups that exist in three dimensions, most are assigned to only one lattice system, in which case both the crystal and lattice systems have the same name. However, five point groups are assigned to two lattice systems, rhombohedral and hexagonal, because both exhibit threefold rotational symmetry. These point groups are assigned to the trigonal crystal system.

A crystal family is determined by lattices and point groups. It is formed by combining crystal systems that have space groups assigned to a common lattice system. In three dimensions, the hexagonal and trigonal crystal systems are combined into one hexagonal crystal family.

Five of the crystal systems are essentially the same as five of the lattice systems. The hexagonal and trigonal crystal systems differ from the hexagonal and rhombohedral lattice systems. These are combined into the hexagonal crystal family.

The relation between three-dimensional crystal families, crystal systems and lattice systems is shown in the following table:

Note: there is no "trigonal" lattice system. To avoid confusion of terminology, the term "trigonal lattice" is not used.

The 7 crystal systems consist of 32 crystal classes (corresponding to the 32 crystallographic point groups) as shown in the following table below:

The point symmetry of a structure can be further described as follows. Consider the points that make up the structure, and reflect them all through a single point, so that (x,y,z) becomes (−x,−y,−z). This is the 'inverted structure'. If the original structure and inverted structure are identical, then the structure is centrosymmetric. Otherwise it is non-centrosymmetric. Still, even in the non-centrosymmetric case, the inverted structure can in some cases be rotated to align with the original structure. This is a non-centrosymmetric achiral structure. If the inverted structure cannot be rotated to align with the original structure, then the structure is chiral or enantiomorphic and its symmetry group is enantiomorphic.^[1]

A direction (meaning a line without an arrow) is called polar if its two-directional senses are geometrically or physically different. A symmetry direction of a crystal that is polar is called a polar axis.^[2] Groups containing a polar axis are called polar. A polar crystal possesses a unique polar axis (more precisely, all polar axes are parallel). Some geometrical or physical property is different at the two ends of this axis: for example, there might develop a dielectric polarization as in pyroelectric crystals. A polar axis can occur only in non-centrosymmetric structures. There cannot be a mirror plane or twofold axis perpendicular to the polar axis, because they would make the two directions of the axis equivalent.

The crystal structures of chiral biological molecules (such as protein structures) can only occur in the 65 enantiomorphic space groups (biological molecules are usually chiral).

There are seven different kinds of lattice systems, and each kind of lattice system has four different kinds of centerings (primitive, base-centered, body-centered, face-centered). However, not all of the combinations are unique; some of the combinations are equivalent while other combinations are not possible due to symmetry reasons. This reduces the number of unique lattices to the 14 Bravais lattices.

The distribution of the 14 Bravais lattices into 7 lattice systems is given in the following table.

In geometry and crystallography, a Bravais lattice is a category of translative symmetry groups (also known as lattices) in three directions.

Such symmetry groups consist of translations by vectors of the form

R = n₁a₁ + n₂a₂ + n₃a₃,

where n₁, n₂, and n₃ are integers and a₁, a₂, and a₃ are three non-coplanar vectors, called primitive vectors.

These lattices are classified by the space group of the lattice itself, viewed as a collection of points; there are 14 Bravais lattices in three dimensions; each belongs to one lattice system only. They^{[clarification needed]} represent the maximum symmetry a structure with the given translational symmetry can have.

All crystalline materials (not including quasicrystals) must, by definition, fit into one of these arrangements.

For convenience a Bravais lattice is depicted by a unit cell which is a factor 1, 2, 3, or 4 larger than the primitive cell. Depending on the symmetry of a crystal or other pattern, the fundamental domain is again smaller, up to a factor 48.

The Bravais lattices were studied by Moritz Ludwig Frankenheim in 1842, who found that there were 15 Bravais lattices. This was corrected to 14 by A. Bravais in 1848.

In two-dimensional space, there are four crystal systems (oblique, rectangular, square, hexagonal), four crystal families (oblique, rectanguar, square, hexagonal), and four lattice systems (oblique, rectangular, square, and hexagonal).^[3][4]

‌The four-dimensional unit cell is defined by four edge lengths (a, b, c, d) and six interaxial angles (α, β, γ, δ, ε, ζ). The following conditions for the lattice parameters define 23 crystal families

The names here are given according to Whittaker.^[5] They are almost the same as in Brown et al.,^[6] with exception for names of the crystal families 9, 13, and 22. The names for these three families according to Brown et al. are given in parentheses.

The relation between four-dimensional crystal families, crystal systems, and lattice systems is shown in the following table.^[5][6] Enantiomorphic systems are marked with an asterisk. The number of enantiomorphic pairs is given in parentheses. Here the term "enantiomorphic" has a different meaning than in the table for three-dimensional crystal classes. The latter means, that enantiomorphic point groups describe chiral (enantiomorphic) structures. In the current table, "enantiomorphic" means that a group itself (considered as a geometric object) is enantiomorphic, like enantiomorphic pairs of three-dimensional space groups P3₁ and P3₂, P4₁22 and P4₃22. Starting from four-dimensional space, point groups also can be enantiomorphic in this sense.

• Crystal cluster – Group of crystals formed in an open space with form determined by their internal crystal structure
• Crystal structure – Ordered arrangement of atoms, ions, or molecules in a crystalline material
• List of space groups
• Polar point group – symmetry in geometry and crystallographyPages displaying wikidata descriptions as a fallback

• Hahn, Theo, ed. (2002). International Tables for Crystallography, Volume A: Space Group Symmetry. Vol. A (5th ed.). Berlin, New York: Springer-Verlag. doi:10.1107/97809553602060000100. ISBN 978-0-7923-6590-7.

• Overview of the 32 groups
• Mineral galleries – Symmetry
• all cubic crystal classes, forms, and stereographic projections (interactive java applet)
• Crystal system at the Online Dictionary of Crystallography
• Crystal family at the Online Dictionary of Crystallography
• Lattice system at the Online Dictionary of Crystallography
• Conversion Primitive to Standard Conventional for VASP input files Archived 2021-11-26 at the Wayback Machine
• Learning Crystallography