All tracks written by Holland–Dozier–Holland except as noted.
- "Where Did Our Love Go" - 2:33
- "Run, Run, Run" - 2:16
- "Baby Love" - 2:39
- "When the Lovelight Starts Shining Through His Eyes" - 3:05
- "Come See About Me" - 2:44
- "Long Gone Lover" (Smokey Robinson) - 2:27
- "I'm Giving You Your Freedom" - 2:40
- "A Breathtaking Guy" (Robinson) - 2:25
- "He Means the World to Me" (Norman Whitfield) - 2:00
- "Standing at the Crossroads of Love" - 2:27
- "Your Kiss of Fire" (Robert Gordy, Harvey Fuqua) - 2:48
- "Ask Any Girl" - 3:00
2004 Expanded CD bonus tracklist
edit
- "This Is It" (Faye Hale) ****
- "I'm The Exception To The Rule" (Whitfield) **
- "Everyday I'll Love You More Than Yesterday" (Robinson, Claudette Rogers Robinson) *
- "Beginning To The Ending" (George Fowler) *****
- "Mr. Blues" (Robinson) *
- "Come On Boy" (Berry Gordy, Jr.) ***
- "Bye Baby" (Gordy) ***
- "My Imagination" (Richard Parker, Faye Hale) ****
- "I Idolize You" (Robinson) *
- "You're Gonna Come To Me" (Gordy) (Version 4 - Credited as Version "3")
- "Honey Babe" (Gordy, Stevie Wonder) ***
- "Penny Pincher"
- "Let Me Hear You Say (I Love You)" (Andre Williams, Johnny Bristol) ********
- "Don't Take It Away" (William Weatherspoon, William "Mickey" Stevenson) *******
- "Just Call Me" (Ivy Jo Hunter, Stevenson) ******
- "That's A Funny Way" (Hunter, Stevenson) ******
- "Stop, Look & Listen" (Ed Cobb) ***
- "Send Me No Flowers"
- "Baby Love" (Alternate "early" version)
- "Introduction/Devil's Den" (Live (Live 1964)
- "When The Lovelight Starts Shining Through His Eyes" (Live 1964)
- "A Breathtaking Guy" (Live 1964)
- "Your Heart Belongs To Me" (Live 1964)
- "Let Me Go The Right Way" (Live 1964)
- "I Am Woman, You Are Man" (Jule Styne, Bob Merrill) (Live 1964)
- "People" (Merrill, Styne) (Live 1964)
- "Where Did Our Love Go" (Live 1964)
- Diana Ross, Florence Ballard, and Mary Wilson – lead and background vocals
- The Four Tops, and Holland–Dozier–Holland – background vocals on "When the Lovelight Starts Shining Through His Eyes", "Run, Run, Run" and "Penny Pincher"
- The Love-Tones – background vocals on "Standing on the Crossroads of Love", "This Is It" and "My Imagination"
- Brian Holland, Lamont Dozier – producers on all tracks except noted below
- Smokey Robinson – producer on "Long Gone Lover" and "A Breathtaking Guy" (and bonus track *)
- Norman Whitfield – producer on "He Means the World to Me" (and bonus track **)
- Robert Gordy – producer on "Your Kiss of Fire"
- Berry Gordy, Jr. – producer on bonus track ***
- Faye Hale – producer on bonus track ****
- George Fowler – producer on bonus track *****
- Ivy Jo Hunter, William "Mickey" Stevenson – producer on bonus track ******
- William "Mickey" Stevenson – producer on bonus track *******
- Andre Williams – producer on bonus track ********
- The Funk Brothers – instrumentation[4]
- Earl Van Dyke – piano on "Where Did Our Love Go", "Baby Love" and "Come See About Me"
- Robert White – guitar on "Where Did Our Love Go"
- Eddie Willis – guitar on "Where Did Our Love Go" and "Baby Love"
- Joe Messina – guitar on "Come See About Me"
- James Jamerson – bass on "Where Did Our Love Go", "Baby Love" and "Come See About Me"
- Richard "Pistol" Allen – drums on "Where Did Our Love Go" and "Baby Love"
- Uriel Jones – drums on "Come See About Me"
- Jack Ashford – vibraphone on "Where Did Our Love Go", "Baby Love" and "Come See About Me"
- Andrew "Mike" Terry – baritone saxophone on "Where Did Our Love Go", "Baby Love" and "Come See About Me"
- Hank Cosby – tenor saxophone on "Baby Love" and "Come See About Me"
- Mike Valvano – footstomps on "Where Did Our Love Go", "Baby Love" and "Come See About Me"
- Bernard Yeszin, Wallace Mead – cover design
- "A Breath Taking, First Sight Soul Shaking, One Night Love Making, Next Day Heart Breaking Guy" b/w "(The Man with the) Rock And Roll Banjo Band" (from The Supremes Sing Country, Western and Pop) (Motown 1044, June 12, 1963, reissued immediately with A-side title shortened to "A Breath Taking Guy")
- "When The Lovelight Starts Shining Through His Eyes" b/w "Standing at the Crossroads of Love" (Motown 1051, October 31, 1963)
- "Run, Run, Run" b/w "I'm Giving You Your Freedom" (Motown 1054, February 7, 1964)
- "Where Did Our Love Go" b/w "He Means the World to Me" (Motown 1060, June 17, 1964)
- "Baby Love" b/w "Ask Any Girl" (Motown 1066, September 17, 1964)
- "Come See About Me" b/w "You're Gone, But Always in My Heart" (on The Supremes Sing Holland–Dozier–Holland) (Motown 1068, October 27, 1964)